Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand.
نویسندگان
چکیده
A new polymeric approach, based on cyanocarbanion ligands, for the design of spin crossover (SCO) compounds led us to the compound [Fe(abpt)(2)(tcpd)] () (tcpd(2-) = (C[C(CN)(2)](3))(2-), abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) which has been characterised as the first SCO molecular chain involving a cyanocarbanion as bridging ligand.
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عنوان ژورنال:
- Chemical communications
دوره 23 شماره
صفحات -
تاریخ انتشار 2009